Effects of Pd and Co intimacy in Pd-modified Co/TiO<sub>2</sub> catalysts for direct CO<sub>2</sub> hydrogenation to fuels: the closer not the better

Scarfiello, Canio; Durupt, Aurélien; Tison, Yann; Minh, Doan Pham; Soulantica, Katerina; Serp, Philippe

doi:10.1039/d4cy00324a

Catal. Sci. Technol.

2024

DOI: 10.1039/d4cy00324a

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Effects of Pd and Co intimacy in Pd-modified Co/TiO₂ catalysts for direct CO₂ hydrogenation to fuels: the closer not the better

Canio Scarfiello,

Aurélien Durupt,

Yann Tison

et al.

Abstract: The direct CO2 hydrogenation to liquid fuels is a sustainable approach to decarbonize the future air transport. This reaction proceeds through a tandem pathway involving the reverse water gas shift...

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References 94 publications

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The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

Molefe,

Forbes,

Coville

2025

Catal. Sci. Technol.

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The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

Molefe,

Forbes,

Coville

2025

Catal. Sci. Technol.

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Advancements in Cobalt-Based Catalysts for Enhanced CO2 Hydrogenation: Mechanisms, Applications, and Future Directions: A Short Review

He,

Wang,

2024

Catalysts

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In 2020, China put forward the national energy and economic development strategy goal of “carbon peak and carbon neutrality”; in this context, the hydrogenation of carbon dioxide into clean energy and high-value-added chemicals can effectively alleviate the current environmental pressure. This process represents a crucial avenue for the advancement of green energy and the realisation of a sustainable energy development strategy. Among the efficient catalysts designed for CO2 hydrogenation reactions, transition metal cobalt has garnered extensive attention from researchers due to its relatively abundant reserves and low economic cost. This paper first introduces the thermodynamic process of carbon dioxide hydrogenation and discusses methods to improve the efficiency of the catalytic reaction from a thermodynamic perspective. It then briefly describes the reaction mechanism of cobalt-based catalysts in the carbon dioxide hydrogenation reaction. Based on this understanding, this paper reviews recent research on the application of cobalt-based catalysts in the hydrogenation of carbon dioxide to produce methane, hydrocarbon chemicals, and alcohols. Finally, the methods to improve the catalytic efficiency of these catalysts are discussed, and future research directions are proposed.

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Effects of Pd and Co intimacy in Pd-modified Co/TiO₂ catalysts for direct CO₂ hydrogenation to fuels: the closer not the better

Abstract: The direct CO2 hydrogenation to liquid fuels is a sustainable approach to decarbonize the future air transport. This reaction proceeds through a tandem pathway involving the reverse water gas shift...

Cited by 2 publications

References 94 publications

The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

Advancements in Cobalt-Based Catalysts for Enhanced CO2 Hydrogenation: Mechanisms, Applications, and Future Directions: A Short Review

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Effects of Pd and Co intimacy in Pd-modified Co/TiO2 catalysts for direct CO2 hydrogenation to fuels: the closer not the better

Abstract: The direct CO2 hydrogenation to liquid fuels is a sustainable approach to decarbonize the future air transport. This reaction proceeds through a tandem pathway involving the reverse water gas shift...

Cited by 2 publications

References 94 publications

The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

Advancements in Cobalt-Based Catalysts for Enhanced CO2 Hydrogenation: Mechanisms, Applications, and Future Directions: A Short Review

Contact Info

Product

Resources

About

Effects of Pd and Co intimacy in Pd-modified Co/TiO₂ catalysts for direct CO₂ hydrogenation to fuels: the closer not the better