Effects of Salty Additives in Drilling Fluids on Hydrate Formation Dynamics and Phase Equilibrium

Abstract

In the drilling process for deepwater and hydrate formations, adding salty components to drilling fluids is an important way to avoid secondary generation of hydrates in the annulus, and the effect of salt solutions on the hydrate generation lays a basis for drilling fluid design. In this study, an evaluation device for the effect of drilling fluid additives on hydrate formation and phase equilibrium is designed based on their interaction characteristics. In addition, hydrate generation experiments were carried out for pure water and three commonly used salty additives for drilling fluids. As such, the hydrate phase equilibrium equations under different conditions are established, and the hydrate phase change latent heat is further calculated. The results show that hydrate formation can be divided into four stages, i.e., gas dissolution, hydrate crystal nucleation, hydrate particle mass aggregation, and stabilization. Compared with pure water, sodium chloride and potassium formate solutions can effectively inhibit hydrate formation. At lower ambient temperature, the higher the concentration of potassium formate, the lower the phase equilibrium pressure. On the contrary, at higher ambient temperature, the higher the concentration of potassium formate, the higher the phase equilibrium pressure. The incomplete presence of sodium silicate in water in the form of ions is found to promote methane hydrate formation. Based on the experimental results of methane hydrate generation in potassium formate and sodium silicate solutions with different mass concentrations, the phase equilibrium calculation models for methane hydrate in both salt solutions were finally established. The latent heat of the phase change distribution of hydrate under different conditions was further calculated. The results of this paper can provide a theoretical basis for the study of deepwater drilling fluid systems and multicomponent annular flow.