The present study experimentally investigated the dynamic spray combustion process of a liquid-centered swirl coaxial injector using liquid oxygen/ methane in an optically accessible liquid rocket engine. Data were obtained at combustor pressures from 0.4 to 1.8 MPa and the ratio of the oxidizer mass flow rate to the fuel rate between 1.32 and 1.55. Liquid oxygen was injected at 120 K, and the injection temperature of gaseous methane was about 285 K. Based on the obtained spatial distribution and oscillation characteristics of liquid oxygen/ methane flame, the combustion process was described by four subprocesses: ignition, low-frequency oscillation combustion, quasi-steady state combustion, and shutdown. In the quasi-steady state combustion subprocess, both the flame length and the normalized flame area are the largest, and the flame expansion angle is the smallest. At the initial stage of combustion, the instability of the liquid oxygen phase state leads to flame instability, which generates low-frequency unstable combustion with a dominant frequency of 93.74 Hz. In addition, the highfrequency (2500−3000 Hz) oscillation of the flame appeared in the whole combustion process. It has been confirmed to be caused by the self-pulsation of spray. Furthermore, with the increase in liquid oxygen manifold pressure, the liquid oxygen phase state changes from a two-phase mixture of liquid and gaseous oxygen to a liquid phase, which increases the mass flow rate of liquid oxygen entering into the combustor, thus generating the increase in the high oscillation frequency of the flame through the whole combustion process.