We report the fabrication of high-electron-mobility Ge(111) n-MOSFETs using a novel and simple approach to passivate a Ge surface by rapid thermal oxidation (RTO). A thin interfacial GeO 2 layer is formed by RTO, which passivates the high-k/Ge interface. The GeO 2 -passivated n-MOSFETs fabricated using a gate-first self-aligned process with high-k/metal gate demonstrate a high peak effective mobility (μ eff ∼ 713 cm 2 · V −1 · s −1 ) with ∼2× enhancement over control Si(100) devices. Moreover, at a drain bias of 1 V and at a gate overdrive of 1.2 V, Ge MOSFETs (L ∼ 75 μm) show a drive current of ∼1.1 mA/ mm, which is ∼1.6× higher than that of the control Si devices. In addition, a good subthreshold slope of ∼130 mV/decade and an I ON /I OFF ratio ∼10 3 were achieved using the GeO 2 interfacial layer formed by RTO.Index Terms-Germanium, high-k dielectric, n-MOSFET.