Effects of solvatomorphism, the nature of a chelating ligand synthon and a counterion on the single crystal XRD structure and SMM properties of paramagnetic monocapped cobalt(ii) tris-pyrazoloximates
Svetlana A. Belova,
Alexander S. Belov,
Anastasia A. Danshina
et al.
Abstract:All the title factors were found to substantially affect the molecular and crystal structure of these pseudomacrobicyclic cobalt(ii) intracomplexes as well as their SMM properties.
The title hybrid iron(II)- and cobalt(III)-centered complexes were prepared in moderate yields using the template reactions of 3-acetylpyrazoloxime as a chelating ligand synthon with a Lewis-acidic zirconium or hafnium(IV) phthalocyaninate...
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