e feasibility of removal of sulfate ions from the sodium alkali FGD wastewater using the ettringite precipitation method was evaluated. Factors affecting the removal of sulfate ions, such as NaAlO 2 dosage, Ca(OH) 2 dosage, solution temperature, anions (Cl − , NO 3 − and F − ), and heavy metal ions (Mg 2+ and Mn 2+ ), were investigated, and the optimal experimental conditions for the removal of sulfate ions were determined. Experimental results indicate that the ettringite precipitation method can effectively remove SO 4 2− with removal efficiency of more than 98%. All the investigated factors have influences on the removal of sulfate ions, and among them, the dosage of reagents, solution temperature, and fluoride ions have the strongest influence. In addition, the method can effectively synergistically remove F − and heavy metal ions with removal efficiencies of more than 90% and 99%, respectively; meanwhile, Cl − and NO 3 − also can be removed minimally by the method. e result of actual wastewater treatment shows that the method is feasible for treating high-concentration sulfate wastewater. e ettringite precipitation method has the potential to be a commercial application in the future.