Chemical composition around diamond/silicon heterointerfaces fabricated by surface activated bonding at room temperature is examined by energy dispersive X-ray spectroscopy under scanning transmission electron microscopy. Iron impurities segregate just on the bonding interfaces, while oxygen impurities segregate off the bonding interfaces in the silicon side by 3-4 nm. Oxygen atoms would segregate so as to avoid the amorphous compound with silicon and carbon atoms, self-organized at the bonding interfaces in the surface activated bonding process. When the bonding interfaces are annealed at 1000 oC, the amorphous compound converts into cubic silicon carbide (c-SiC), and nano-voids 5-15 nm in size are formed at the region between silicon and c-SiC, at which the oxygen density is high before annealing. The nano-voids can act as the gettering sites in which metal impurities are preferentially agglomerated, and the impurity gettering would help to improve the electronic properties of the bonding interfaces by annealing.