Joints are the weak plane structures in coal. The existence of joints leads to coal failure, with different fracture modes and energy evolution laws. In this paper, the energy evolution and bursting liability index of coal failure with different joint inclination angles (JIAs) are analyzed. The results show that with an increase in joint inclination angle (JIA), the total energy and elastic energy of coal first decrease and then increase and the dissipation energy decreases gradually. The existence of joints changes the bursting liability of coal. With an increase in the JIA, the uniaxial compressive strength (Rc) of coal first decreases and then increases, the dynamic failure time (DT) gradually decreases, and the impact energy velocity index (WST) and the impact energy index (KE) gradually increase. With an increase in the JIA, coal went from tensile failure to shear failure and tension shear mixed failure. After coal failure, the fractal dimension was between 1.7 and 2.4, decreasing first and then increasing; the larger the JIA and the degree of fragmentation, the more energy consumed at the moment of failure and the stronger the bursting liability of coal. The results have a guiding significance for the monitoring and prevention of rock bursts in coal mines.