Abstract. Since early 2020, the COVID-19 pandemic has led to
lockdowns at national scales. These lockdowns resulted in large cuts of
atmospheric pollutant emissions, notably related to the vehicular traffic
source, especially during spring 2020. As a result, air quality changed in
manners that are still currently under investigation. The robust
quantitative assessment of the impact of lockdown measures on ambient
concentrations is however hindered by weather variability. In order to
circumvent this difficulty, an innovative methodology has been developed.
The Analog Application for Air Quality (A3Q) method is based on the
comparison of each day of lockdown to a group of analog days having similar
meteorological conditions. The A3Q method has been successfully
evaluated and applied to a comprehensive in situ dataset of primary and
secondary pollutants obtained at the SIRTA observatory, a suburban
background site of the megacity of Paris (France). The overall slight decrease
of submicron particulate matter (PM1) concentrations (−14 %) compared to business-as-usual
conditions conceals contrasting behaviors. Primary traffic tracers
(NOx and traffic-related carbonaceous aerosols) dropped by 42 %–66 %
during the lockdown period. Further, the A3Q method enabled us to
characterize changes triggered by NOx decreases. Particulate nitrate
and secondary organic aerosols (SOAs), two of the main springtime aerosol
components in northwestern Europe, decreased by −45 % and −25 %,
respectively. A NOx relationship emphasizes the interest of NOx
mitigation policies at the regional (i.e., city) scale, although long-range
pollution advection sporadically overcompensated for regional decreases.
Variations of the oxidation state of SOA suggest discrepancies in SOA
formation processes. At the same time, the expected ozone increase
(+20 %) underlines the negative feedback of NO titration. These results
provide a quasi-comprehensive observation-based insight for mitigation
policies regarding air quality in future low-carbon urban areas.