In order to prevent the copper coating on the carbon fiber surface from oxidizing and falling off, the tin coating is plated on the surface of copper-coated carbon fiber. In this paper, the copper-tin composite coating with different thicknesses of tin coatings were successfully prepared by electroless plating. The results show that with the increasing of electroless tin plating time, the thickness of the copper-tin composite coating increases. The test results of the bonding force between the composite coating and the carbon fiber show that the coating bonding force is the best when the thickness of composite coating is between 1.31 μm and 1.55 μm. This is due to the formation of copper-tin intermetallic compounds preventes direct contact between the copper coating and oxygen, which can effectively inhibit the oxidation of the copper plating layer, thereby making the plating layer less likely to fall off. However, the excessively thick tin coating would increase the internal stress of the coating, and promote the generation of cracks on the surface of the composite coating, which would cause the composite coating to fall off. This research will provide new ideas for the preparation of high-performance copper plating on the surface of carbon fiber, and provide an important theoretical and practical basis for the application of copper coatings.