The
extensive use of selective catalytic reduction (SCR) catalysts
will afford many spent SCR catalysts. The mass fraction of the titanium
component is over 80% in spent SCR catalysts, but currently, it is
usually thrown away without proper recycling. This work aims to develop
a clean, green, and economical approach to recovering titanium and
regenerating TiO2 photocatalysts from spent SCR catalysts
based on the conversion of the titanium component. This titanium component
is converted into metastable α-Na2TiO3 with high efficiency (>98%) using a NaOH molten salt method,
and
the optimal conditions were found to be a roasting temperature of
550 °C, a NaOH-to-spent-SCR-catalysts mass ratio of 1.8:1, a
roasting time of 10 min, and a NaOH concentration of 60–80
wt %. And a possible chemical reaction mechanism is proposed. A subsequent
hydrothermal treatment of α-Na2TiO3 regenerates
TiO2 photocatalysts with high purity (>99.0%) that can
satisfy commercial requirements. In addition, the present iron element
contained in spent SCR catalysts is doped into regenerated TiO2 photocatalysts, resulting in providing visible-light-driven
photocatalytic activities. The regenerated TiO2 photocatalysts
possess superior photocatalytic degradation capacities for dye pollutants
and can be used to efficiently treat wastewater. This work introduces
a promising technology for the cyclical regeneration of titanium from
spent SCR catalysts.