The identification of the characteristics of each movement and its adjustment to the training goals are tasks that demand the interaction of many knowledge areas. These tasks are essential to the success in sports activities and training programs designed with athletic, aesthetic or healthy purposes. The objective of the present study was to compare the electromyographic (EMG) activity of the pectoralis major (PM), anterior deltoids (DA) and triceps brachii (TB) muscles during the barbell bench press (SP) and the peck deck (PD) exercises. EMG activity of TB, PM and DA were assessed during 10 maximum repetitions performed in SP and PD in 13 trained men. The results did not show any differences between exercises for PM and DA activity; however, TB activity was higher for SP than PD exercise. During SP, the PM muscle activity was higher than TB. There were no differences between PM and DA, or between DA and TB. During the PD exercise, the PM and DA muscle activities were higher than TB. There were no differences between PM and DA. It was concluded that the prime movers of both exercise are DA and PM, and there are no differences between them. Therefore, both PD and SP could be performed with the purpose to stimulate DA and PM muscles, depending on the availability of the equipments and/or the specificity of the motor tasks.