Nitrogen dioxide (NO
2
) is an active species
of exhaust
gas recirculation gas, and it has a significant impact on the autoignition
and combustion processes of fuels. This study presented a comprehensive
investigation of the effect of NO
2
on the combustion characteristics
of the
n
-butanol/biodiesel dual fuel. Experiments
were conducted on a single-cylinder engine with 0, 100, 200, and 400
v/v ppm NO
2
addition at two fuel injection ratios. The
findings of the experiments indicated that adding NO
2
resulted
in an earlier start of heat release and an increase in peak in-cylinder
pressure as compared to experiments where no NO
2
was added.
The evolutions of
n
-butanol, biodiesel, and OH radicals
were evaluated using the computational fluid dynamics software coupled
with the
n
-butanol–biodiesel–NO
2
mechanism. The results revealed that when 400 v/v ppm NO
2
was added, the consumption of
n
-butanol
and biodiesel occurred earlier, and the formation of OH radicals was
approximately an order of magnitude higher before the biodiesel was
injected. Furthermore, reaction rate and flux analyses were performed
to understand the effect of NO
2
addition on the reaction
process. When NO
2
was added, 35% of the HO
2
radicals
reacted with NO which converted from NO
2
via the reaction
NO + HO
2
⇌ NO
2
+ OH, promoting the formation
of OH radicals in the reaction system. The addition of NO
2
can also enhance the consumption of CH
3
radicals via
the reaction CH
3
+ HO
2
⇌ CH
3
O + OH.