In
imparting wetting properties, a fabrication process without
the addition of new compounds and deposition of coating layers would
be the most desirable because it does not introduce additional complexities.
Hence, the ion beam irradiation technique is used as it enables the
chemistry of materials to be modified through simple adjustments of
irradiation parameters such as the type of accelerated particles,
beam energy, and fluence. In this study, the hydrophilicity of alumina
surfaces was weakened by irradiating He ion beams of different energy
levels (200 keV and 20 MeV). These transitions become more pronounced
as the total beam fluence increases. In low-energy irradiation, the
effect of irradiation is predominant near the surface, and hydrophilicity
is weakened by the increase in carbon adsorption and suppression of
dissociative adsorption of water molecules owing to the introduction
of oxygen vacancies. In contrast, nuclear transmutations are induced
by irradiation with high-energy beams. Consequently, fluorine is generated,
and hydrophobic functional groups are formed on the surface. By varying
the beam conditions, the wetting properties of the target ceramic
can be controlled to the desired level, which is required in various
industries, via appropriate adjustments of the beam parameters. In
addition, the beam irradiation technique may be applicable to all
ceramic materials, including lattice oxygen and alumina.