Efficacy of clay materials for ciprofloxacin antibiotic analysis in urine and pharmaceutical products

Azriouil, M.; Aghris, S.; Matrouf, M.; Loudiki, A.; Laghrib, F.; Farahi, A.; Bakasse, M.; Saqrane, S.; Lahrich, S.; Mhammedi, M.A. El

doi:10.1016/j.matchemphys.2022.125787

Cited by 14 publications

(11 citation statements)

References 60 publications

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“…As it can be seen, the diffractograms of pure clay demonstrates the presence of all characteristic peaks, as previously described by us in more detail. 43 Moreover, the XRD pattern related to the rGO-Clay composite showed all the clay's peaks. However, it must be noted that within the modification of clay with rGO, some changes in 2θ°p osition/ intensity were observed, which may be owing to the changes in the textural properties of clay samples by the presence of GO and rGO on the external and internal surface.…”

Section: Resultsmentioning

confidence: 97%

“…The treatment procedure and clay compositions were presented in an earlier published article. 43 Briefly, the raw clay samples were exhaustedly crumpled, and the obtained powder was treated with hydrochloride acid (HCl 0.3 mol l −1 ) during 3 h per day, repeated for 9 d in order to remove the carbonates (CaCO 3 , CaMg (CO 3 ) 2 . Subsequently, the suspension is transferred to a beaker and washed several times to remove the excess of HCl and allow the clay particles to deflocculate.…”

Section: Methodsmentioning

confidence: 99%

“…Then, the fine particles (fraction < 2 μm) were collected according to the stock low as previously detailed. 43 The rGO-Clay composite was prepared by the following procedures: 75 mg of clay microparticles was dispersed in an aqueous solution containing GO followed by vigorous sonication and agitation for 24 h at ambient temperature in order to obtain a homogenous colloidal solution of GO/Clay. The obtained GO/Clay solution was subjected to a temperature treatment within the range of 100 °C to 500 °C (Scheme 1).…”

Section: Methodsmentioning

confidence: 99%

“…Based on Eq. 6, the LOD (3 × sd blank /p) 43 and the sensitivity of rGO-Clay-CPE for Cipro sensing are calculated as 7.7 nM and 11.24 μA μM −1 cm −2 , respectively. Dual range in the recognition of Cipro might be credited to the unavoidable adsorption of Cipro on the rGO-Clay-CPE surface as the concentration increases leading to hampered its diffusion.…”

Section: Effect Of Incubation Timementioning

confidence: 99%

“…The preparation procedures and complementary information on the urine and tablet samples were previously detailed by us. 43 Briefly, the collected urine samples were centrifuged at 4000 rpm for 10 min and the supernatant flowed by a simple filtration using a microporous filter of 0.45 mm and then diluted 3 times using 0.1 M PB. Then, the Cipro was added to the obtained solution to get the required concentration.…”

Section: Effect Of Incubation Timementioning

confidence: 99%

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Eco-Friendly Elaborated Clay-Supported Reduced Graphene Oxide for the Determination of Antibacterial Ciprofloxacin in Wastewater, Urine, and Drug Samples

Azriouil,

Chhaibi,

Hrioua

et al. 2023

J. Electrochem. Soc.

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The accumulation of pharmaceutical residues in the environment can indeed lead to a wide range of environmental problems which can have a negative impact on human health through various pathways. For this reason, it is of great importance to develop a rapid and sensitive strategy to monitor the accumulation of pharmaceutical residues, ultimately safeguarding both the environment and human health. Here, the development of a carbon paste electrode modified by clay-supported reduced graphene oxide (rGO-Clay-CPE) is described. This sensor was used for the electrochemical detection of ciprofloxacin (Cipro). The rGO-Clay material was synthesized based on the thermal reduction of GO. Then, it was characterized by means of X-ray diffraction and scanning electron microscopy. Using differential pulse voltammetry (DPV), the prepared electrode shows high electrochemical performance towards the oxidation of Cipro. Under the optimized conditions, the DPV at the rGO-Clay sensor showed that the electro-analytical signal of Cipro is linearly related to the concentration in the range of 0.08–2.0-50.0 µM with a sensitivity of 11.24 µA µM-1 cm-2 and a limit of detection of 7.7 nM. The developed sensor has successfully been applied for Cipro monitoring in wastewater, urine, and drug samples with acceptable outcomes.

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Section: Resultsmentioning

confidence: 97%

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Section: Effect Of Incubation Timementioning

confidence: 99%

Section: Effect Of Incubation Timementioning

confidence: 99%

See 3 more Smart Citations

Eco-Friendly Elaborated Clay-Supported Reduced Graphene Oxide for the Determination of Antibacterial Ciprofloxacin in Wastewater, Urine, and Drug Samples

Azriouil,

Chhaibi,

Hrioua

et al. 2023

J. Electrochem. Soc.

Self Cite

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Ultrasensitive monitoring of Ciprofloxacin with green reduced graphene oxide@clay composite

Azriouil,

Hrioua,

Chhaibi

et al. 2024

Electroanalysis

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Green Synthesis of Clay/rGO Composite for Sensitive Detection of Para Nitrophenol in the Environment

Laghrib,

Azriouil,

Aghris

et al. 2024

ChemistrySelect

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Nitrophenols (e. g., para nitrophenol), although they have beneficial properties, their residuals are injurious to the environment owing to their high lethal potential for many categories of nature (e. g. animals, humans, plants, etc.), which require their monitoring. In this paper, a new Clay/green reduced graphene oxide composite (Clay/rGO) was efficaciously synthesized and utilized as an excellent modifier for carbon paste electrode (CPE) for the electro‐analytical determination of paranitrophenol (PNØ). The electrochemical futures and reduction of PNØ at the surface of the as‐prepared Clay/rGO˧CPE have been executed using DPV differential pulse voltammetry (DPV), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The use of the EIS provided that the Clay/rGO˧CPE facilitate the electron exchange process. By using the DPV technique in phosphate buffer (PB) under biological pH (7) (PB_7) the prepared monitor exhibited an excellent linearity relationship in the concentration ranges from 1.0 to 1000.0 μM with a detection limit (DL=3×σ/P) of 0.16 μM and a quantification limit of (QL=10×σ/P) of 0.54 μM. The Clay/rGO˧CPE offered high selectivity and a satisfactory concert in the electroanalytical sensing of PNØ in wastewater sample.

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Efficacy of clay materials for ciprofloxacin antibiotic analysis in urine and pharmaceutical products

Cited by 14 publications

References 60 publications

Eco-Friendly Elaborated Clay-Supported Reduced Graphene Oxide for the Determination of Antibacterial Ciprofloxacin in Wastewater, Urine, and Drug Samples

Eco-Friendly Elaborated Clay-Supported Reduced Graphene Oxide for the Determination of Antibacterial Ciprofloxacin in Wastewater, Urine, and Drug Samples

Ultrasensitive monitoring of Ciprofloxacin with green reduced graphene oxide@clay composite

Green Synthesis of Clay/rGO Composite for Sensitive Detection of Para Nitrophenol in the Environment

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