Nd 3+ -doped LiLuF 4 single crystal with high optical quality was grown by Czochralski technique. The segregation coefficient of Nd 3+ in LiLuF4 crystal was determined by the inductively coupled plasma atomic emission spectrometry method. Polarized absorption and fluorescence spectra were investigated. The peak absorption cross section at 792 nm and peak emission cross section at 1053 nm are 6.94×10−20 and 7.60×10 −20 cm 2 , respectively. With a laser-diode as the pump source, a maximum 6.22 W continuous-wave laser output at 1053 nm has been obtained with a slope efficiency of 37.2% with respect to the pump power. Output power as a function of the incident pump power for the Nd:LiLuF4 laser