Lasers with a wavelength of 2-μm have important application prospects in those civil and military fields such as laser medical surgery, atmospheric monitoring, remote sensing, due to the strong absorption in water and its eye-safe characteristic 1 . In this research, Ho 3+ ion is a promising candidate for 2 and 2.9 μm lasers owing to the 5 I 7 → 5 I 8 and 5 I 6 → 5 I 7 transitions, respectively. However, it can not be obtained efficiently due to the lack of absorption bands matched with commercial 808 and/or 980 nm laser diodes (LDs). Therefore, sensitized excitation with rare-earth and/or semimetal codoping such as Tm 3+