Efficient Asymmetry Generation in the Synthesis of Oxo‐Rhenium(<scp>V</scp>) Complex cis‐[ReOCl2{OCMe2CMe2OP(OCMe2CMe2O)}py]

Hybrid architectures: Self‐organization of the xylyl‐linked dicobalt(III) complex with an L‐cysteine residue into homochiral dimeric and helix supramolecular structures is reported (see figure). These two structures were randomly and exclusively formed in the absence of any external stimuli if [HgBr4]2− was incorporated as the counter ion, thanks to the conformational bistability of the xylyl linker.

show abstract

Autocatalytic Creation of Closed Dimer and Extended Helix Metallosupramolecular Architectures

Yoshinari

Konno

2009

Chemistry A European J

View full text Add to dashboard Cite

show abstract

Stereoselective Aldol Addition to Rhenium(I) Complexes and Reversible Dimerization with Epimerization of the Metal Center

Álvarez

Carrillo

García‐Rodríguez

et al. 2013

Chemistry A European J

View full text Add to dashboard Cite

Herein, we report several examples of stereoselective aldol additions of aldehydes or ketones to ReI tricarbonyl complexes to form monomeric derivatives in good yields. The metal-centered chirality defines the final stereochemistry of the carbon atom of the monomeric ReI complex after the addition. However, it cannot control the resulting stereochemistry of the enolate part, and thus, if the α-carbon atom of the reagent is prochiral, a mixture of diastereoisomers is obtained. On the other hand, all of the monomeric complexes can be reversibly dimerized in basic media to form cis dimers, for which an epimerization of the metal-centered chirality is required in order to avoid steric congestion. All of these results are supported by exhaustive crystallographic analysis.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Efficient Asymmetry Generation in the Synthesis of Oxo‐Rhenium(V) Complex cis‐[ReOCl₂{OCMe₂CMe₂OP(OCMe₂CMe₂O)}py]

Cited by 2 publications

References 29 publications

Autocatalytic Creation of Closed Dimer and Extended Helix Metallosupramolecular Architectures

Autocatalytic Creation of Closed Dimer and Extended Helix Metallosupramolecular Architectures

Stereoselective Aldol Addition to Rhenium(I) Complexes and Reversible Dimerization with Epimerization of the Metal Center

Contact Info

Product

Resources

About

Efficient Asymmetry Generation in the Synthesis of Oxo‐Rhenium(V) Complex cis‐[ReOCl2{OCMe2CMe2OP(OCMe2CMe2O)}py]

Cited by 2 publications

References 29 publications

Autocatalytic Creation of Closed Dimer and Extended Helix Metallosupramolecular Architectures

Autocatalytic Creation of Closed Dimer and Extended Helix Metallosupramolecular Architectures

Stereoselective Aldol Addition to Rhenium(I) Complexes and Reversible Dimerization with Epimerization of the Metal Center

Contact Info

Product

Resources

About

Efficient Asymmetry Generation in the Synthesis of Oxo‐Rhenium(V) Complex cis‐[ReOCl₂{OCMe₂CMe₂OP(OCMe₂CMe₂O)}py]