2019
DOI: 10.1016/j.cej.2019.01.175
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Efficient H2O2 electrogeneration at graphite felt modified via electrode polarity reversal: Utilization for organic pollutants degradation

Abstract: Electrochemical synthesis of H 2 O 2 offers a great potential for water treatment. However, a significant challenge is the development of efficient cathode materials for the process. Herein, we implement a practical electrochemical cathode modification to support efficient H 2 O 2 electrogeneration via the reduction of dissolved anodic O 2. Graphite felt (GF) is in situ anodically *

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Cited by 84 publications
(33 citation statements)
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References 71 publications
(85 reference statements)
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“…4 b shows that while the interaction of A with the AC source, B seems to be irrelevant for the CR% result, the interaction of A with the particle size distribution defined by C, seems to have a moderate effect. This observation supports the inter-particle contact and derived electric conductivity effect that has been previously suggested for C and that should depend up to a certain point on A, since the pre-treatment oxidation process influences the hydrophilicity as well as the chemical composition of the surface of the AC material [ 27 , [55] , [56] , [57] , [58] ].…”
Section: Resultssupporting
confidence: 88%
“…4 b shows that while the interaction of A with the AC source, B seems to be irrelevant for the CR% result, the interaction of A with the particle size distribution defined by C, seems to have a moderate effect. This observation supports the inter-particle contact and derived electric conductivity effect that has been previously suggested for C and that should depend up to a certain point on A, since the pre-treatment oxidation process influences the hydrophilicity as well as the chemical composition of the surface of the AC material [ 27 , [55] , [56] , [57] , [58] ].…”
Section: Resultssupporting
confidence: 88%
“…Furthermore, the oxygen functional groups on carbon materials were increased by the treatments of acid, alkali, electrochemical oxidation, and glow discharge plasma. All of these materials showed excellent properties of two-electron ORR [33][34][35][36][37][38]. These reports have proven that oxygen functional groups on carbon materials are effective for selective O 2 reduction to produce H 2 O 2 .…”
Section: Oxygen-doped Carbonaceous Materialsmentioning
confidence: 83%
“…H2O2 [52] 。Garcia-Rodriguez 等 [53] [52] 。氧基官能团(-COOH、-C=O、-OH、C-O-C 等) 作为 O2 电化学还原活性位点已被频繁报道 [56] 。有研 究发现,具有亲水性的氧基官能团(-COOH、-COH、 -COO-、R-OH、>C=O),易于接触电极表面产生溶 解 O2 [57] 。同时,氧基官能团浓度和 H2O2 产量之间存 在明显线性相关性 [58,59] 。Lu 等 [60]…”
Section: Figureunclassified