2011
DOI: 10.1103/physreva.83.045401
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Efficient photoassociation with a train of asymmetric laser pulses

Abstract: The photoassociation (PA) dynamics implemented by a train of asymmetric slowly turned-on and rapidly turned-off (STRT) laser pulses is investigated theoretically with Cs 2 as an example. A higher PA efficiency is achieved by optimizing the parameters of the STRT pulse train. The PA reaction goes partly beyond the scope of the PA window. Numerical calculations show that an efficient population accumulation in the PA process can be realized with the STRT laser-pulse train which is available in the current experi… Show more

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Cited by 28 publications
(23 citation statements)
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“…To obtain the transition factor, the eigenfunctions of bound states {ψ Sl ν } in the grid representation should be precalculated. We calculate the eigenfunctions {ψ Sl ν } using the mapped Fourier grid (MFG) method [23,24].…”
Section: Theoretical Approachmentioning
confidence: 99%
“…To obtain the transition factor, the eigenfunctions of bound states {ψ Sl ν } in the grid representation should be precalculated. We calculate the eigenfunctions {ψ Sl ν } using the mapped Fourier grid (MFG) method [23,24].…”
Section: Theoretical Approachmentioning
confidence: 99%
“…The first peak is much weaker than the second one due to smaller FC overlapping. For φ = π/3 and π/2, much population induced by off-resonant excitation remains on the vibrational states near dissociation limit due to the slight asymmetry of the envelope of the electric field [20,21]. This part of population also makes a contribution to the final PA efficiency.…”
Section: A Dependence Of Pa Efficiency On Poe At a Fixed T Pmentioning
confidence: 99%
“…Apparently the time scale much shorter than the lifetime of the excited electronic state can overcome the losses caused by spontaneous emission. A frequency-domain cutoff and time-domain asymmetric laser pulses have been implemented to avoid atomic transition [18,19] and to maintain more photoassociated molecules caused by off-resonant excitation [20,21].…”
Section: Introductionmentioning
confidence: 99%
“…Photoassociation (PA), forming molecules from atoms of the continuum using the laser pulse, has received considerable attention in recent years [1][2][3][4][5][6][7]. Many PA schemes, for the formation of a stable deeply bound state molecule, contain two steps: the first step is a free-to-bound excitation of scattering states of the collision atom pair to a bound vibrational level in an electronically excited molecular state, and the second is a bound-to-bound transition from the excited to the ground electronic state [8].…”
Section: Introductionmentioning
confidence: 99%