Efficient photocatalytic degradation of sulfasalazine and reduction of hexavalent chromium over robust In2S3/Nd2O3 heterojunction under visible light

Murugalakshmi, M.; Park, Chang Min; Muthuraj, V.

doi:10.1016/j.jwpe.2021.102492

Cited by 11 publications

(2 citation statements)

References 47 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…65-0459). 26,27 Due to the amorphous characteristics of CoS x , only the characteristic peaks attributed to In 2 S 3 were observed in the XRD patterns of CoIS composites. Furthermore, there was a gradual decrease in peak intensity with increasing CoS x content, signifying successful synthesis of the CoIS composite material.…”

Section: Resultsmentioning

confidence: 99%

Metal–Organic Framework-Templated Synthesis of In₂S₃/CoS_x Nanocages for Photocatalytic Removal of Antibiotics

Li,

Liu

et al. 2023

ACS Appl. Nano Mater.

View full text Add to dashboard Cite

Rational design of a hierarchical core−shell structured photocatalyst is crucial for enhancing the separation and transport efficiency of photogenerated carriers, thereby improving the photocatalytic degradation efficiency. In this study, hollow polyhedral CoS x was first synthesized by utilizing dodecahedral Co-based metal−organic framework (ZIF-67) as a Co source and template, followed by introducing In and S species to fabricate hierarchical core−shell In 2 S 3 /CoS x composites. The resulting In 2 S 3 / CoS x porous hollow heterostructured composites exhibited an accelerated interfacial carrier transfer ratio and enhanced photocatalytic removal performance of tetracycline hydrochloride (TCH). Among them, the optimized sample In 2 S 3 /CoS x -2 (CoIS-2) demonstrated the highest TCH removal rate of 0.0324 min −1 , which was 22.8 times higher than that of pristine CoS x and 5.7 times higher than that of pure In 2 S 3 , respectively. Moreover, its apparent quantum efficiency reached 4.66% at 420 nm. Electron spin resonance analysis and active substance capture experiments confirmed that superoxide radical ( • O 2 − ) played a predominant role in the reaction system. Furthermore, we investigated the dynamics of photoinduced carriers through a series of photoelectric tests combined with density functional theory calculations. This study provides valuable insights into controllable construction of metal− organic framework-based materials with high photocatalytic degradation efficiency and stability.

show abstract

Section: Resultsmentioning

confidence: 99%

Metal–Organic Framework-Templated Synthesis of In₂S₃/CoS_x Nanocages for Photocatalytic Removal of Antibiotics

Li,

Liu

et al. 2023

ACS Appl. Nano Mater.

View full text Add to dashboard Cite

show abstract

“…It can be inferred from the foregoing analysis that GO was successfully reduced in the experiment. Additionally, the high-resolution O1s spectra as shown in Figure 2 e demonstrate that the peak at 529.6 eV is associated with the presence of the Co-O bond in the material [ 23 ], the peak at 531.6 eV is attributable to lattice oxygen (Nd/O bond) [ 24 ], and the remaining peak at 530.8 eV is linked to the material capability to adsorb oxygen molecules [ 25 ]. Various positions of peaks can be seen in the high-resolution spectrum of the element Co, where the peak positions at 780.1 eV and 795.3 eV correspond to the typical peaks of Co2p 3/2 and Co2p 1/2 of Co 3 O 4 in the material, respectively, as shown in Figure 2 c. Additionally, it can be seen that the Co2p 3/2 peak has a satellite peak at 781.8.5 eV/780.1 eV and the Co2p 1/2 peak has a satellite peak at 796.7 eV/795.3 eV, indicating that there is a simultaneous presence of Co 2+ and Co 3+ in the material [ 26 ].…”

Section: Resultsmentioning

confidence: 99%

Fabrication of 3D HierarchicalSphericalHoneycomb-Like Nd2O3/Co3O4/Graphene/Nickel Foam Composite Electrode Material for High-Performance Supercapacitors

Liang

Wang

et al. 2023

Materials

View full text Add to dashboard Cite

A 3D hierarchical spherical honeycomb-like composite electrode materialof neodymium oxide (Nd2O3), cobalt tetraoxide (Co3O4), and reduced graphene oxide (rGO) on nickel foam (named as Nd2O3/Co3O4/rGO/NF) were successfully fabricated by combining the hydrothermal synthesis method and the annealing process. Nickel foam with a three-dimensional spatial structure was used as the growth substrate without the use of any adhesives. The Nd2O3/Co3O4/rGO/NF composite has outstanding electrochemical performance and can be used directly as an electrode material for supercapacitors (SCs). By taking advantage of the large specific surface area of the electrode material, it effectively slows down the volume expansion of the active material caused by repeated charging and discharging processes, improves the electrode performance in terms of electrical conductivity, and significantly shortens the electron and ion transport paths. At a 1 A/g current density, the specific capacitance reaches a maximum value of 3359.6 F/g. A specific capacitance of 440.4 F/g with a current density of 0.5A/g is still possible from the built symmetric SCs. The capacitance retention rate is still 95.7% after 30,000 cycles of testing at a high current density of 10 A/g, and the energy density is 88.1 Wh/kg at a power density of 300 W/kg. The outcomes of the experiment demonstrate the significant potential and opportunity for this composite material to be used as an electrode material for SCs.

show abstract

Novel 2D/2D S-scheme Ni doped SnS2/BiOBr heterostructures with enhanced photocatalytic activity

Wang

Huang

et al. 2023

Arabian Journal of Chemistry

View full text Add to dashboard Cite

Efficient photocatalytic degradation of sulfasalazine and reduction of hexavalent chromium over robust In2S3/Nd2O3 heterojunction under visible light

Cited by 11 publications

References 47 publications

Metal–Organic Framework-Templated Synthesis of In₂S₃/CoS_x Nanocages for Photocatalytic Removal of Antibiotics

Metal–Organic Framework-Templated Synthesis of In₂S₃/CoS_x Nanocages for Photocatalytic Removal of Antibiotics

Fabrication of 3D HierarchicalSphericalHoneycomb-Like Nd2O3/Co3O4/Graphene/Nickel Foam Composite Electrode Material for High-Performance Supercapacitors

Novel 2D/2D S-scheme Ni doped SnS2/BiOBr heterostructures with enhanced photocatalytic activity

Contact Info

Product

Resources

About

Efficient photocatalytic degradation of sulfasalazine and reduction of hexavalent chromium over robust In2S3/Nd2O3 heterojunction under visible light

Cited by 11 publications

References 47 publications

Metal–Organic Framework-Templated Synthesis of In2S3/CoSx Nanocages for Photocatalytic Removal of Antibiotics

Metal–Organic Framework-Templated Synthesis of In2S3/CoSx Nanocages for Photocatalytic Removal of Antibiotics

Fabrication of 3D HierarchicalSphericalHoneycomb-Like Nd2O3/Co3O4/Graphene/Nickel Foam Composite Electrode Material for High-Performance Supercapacitors

Novel 2D/2D S-scheme Ni doped SnS2/BiOBr heterostructures with enhanced photocatalytic activity

Contact Info

Product

Resources

About

Metal–Organic Framework-Templated Synthesis of In₂S₃/CoS_x Nanocages for Photocatalytic Removal of Antibiotics

Metal–Organic Framework-Templated Synthesis of In₂S₃/CoS_x Nanocages for Photocatalytic Removal of Antibiotics