Efficient Photothermal Catalytic Oxidation Enabled by Three-Dimensional Nanochannel Substrates

Abstract

Photothermal catalysis exhibits promising prospects to overcome the shortcomings of high-energy consumption of traditional thermal catalysis and the low efficiency of photocatalysis. However, there is still a challenge to develop catalysts with outstanding light absorption capability and photothermal conversion efficiency for the degradation of atmospheric pollutants. Herein, we introduced the Co 3 O 4 layer and Pt nanoclusters into the three-dimensional (3D) porous membrane through the atomic layer deposition (ALD) technique, leading to a Pt/Co 3 O 4 /AAO monolithic catalyst. The 3D ordered nanochannel structure can significantly enhance the solar absorption capacity through the light-trapping effect. Therefore, the embedded Pt/Co 3 O 4 catalyst can be rapidly heated and the O 2 adsorbed on the Pt clusters can be activated to generate sufficient O 2 − species, exhibiting outstanding activity for the diverse VOCs (toluene, acetone, and formaldehyde) degradation. Optical characterization and simulation calculation confirmed that Pt/Co 3 O 4 /AAO exhibited state-of-the-art light absorption and a notable localized surface plasmon resonance (LSPR) effect. In situ diffuse reflectance infrared Fourier transform spectrometry (in situ DRIFTS) studies demonstrated that light irradiation can accelerate the conversion of intermediates during toluene and acetone oxidation, thereby inhibiting byproduct accumulation. Our finding extends the application of AAO's optical properties in photothermal catalytic degradation of air pollutants.

Multistep Quenching of a Rust-Derived Catalyst for Enhanced Volatile Organic Compound Catalytic Oxidation

“…The process of activating toluene to benzoate is regarded as toluene activation . The appearance of benzyl alcohol species (1140 and 1233 cm –1 ) , and benzoate species (1382 cm –1 ) on Pt q /Sn q :Fe 2 O 3 suggested the activation of toluene to benzoate. However, the detection of benzyl alcohol and benzaldehyde (1697 cm –1 ) on Pt q /Fe 2 O 3 implied the activation of toluene to benzaldehyde.…”