Efficient simultaneous removal of Cu(II) and Cr2O72− from aqueous solution by a renewable amphoteric functionalized mesoporous silica

Wu, Qiuping; You, Ruirong; Lv, Qiufeng; Xu, Yali; You, Weijie; Yu, Yan

doi:10.1016/j.cej.2015.07.019

Cited by 34 publications

(13 citation statements)

References 54 publications

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“…As for the Cr(VI) adsorption behaviors, phosphate-P inhibited the adsorption of Cr(VI) on modified kaolin because of competitive adsorption [19]. Cu(II) also gradually decreased the removal efficiency of Cr 2 O 7 2− on mesoporous silica as the pH increased due to protonation [20]. However, Xu et al found that the adsorption of CrO 4 2− on red soil was remarkably enhanced by an increase in both Cu 2+ dose and pH [21].…”

Section: Journal Of Chemistrymentioning

confidence: 99%

“…The concentrations of Cr(III), Cr(VI), and Cu(II) were 300 mg⋅L −1 , 200 mg⋅L −1 , and 200 mg⋅L −1 , respectively. Then, samples were completely mixed using a magnetic stirrer at a speed of 200 rpm and collected at different time intervals (i.e., 5,10,15,20,30,40,60,80, 100, and 120 min). Finally, samples were immediately filtered with 0.45 m polycarbonate filters for further analysis.…”

Section: Batch Adsorption Experimentsmentioning

confidence: 99%

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Effects of Cu(II) on the Adsorption Behaviors of Cr(III) and Cr(VI) onto Kaolin

Liu

et al. 2016

Journal of Chemistry

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The adsorption of Cr(III) or Cr(VI) in the absence and presence of Cu(II) onto kaolin was investigated under pH 2.0–7.0. Results indicated that the adsorption rate was not necessarily proportional to the adsorption capacity. The solutions’ pH values played a key role in kaolin zeta potential(ζ), especially the hydrolysis behavior and saturation index of heavy metal ions. In the presence of Cu(II),qmixCr(III)reached the maximum adsorption capacity of 0.73 mg·g−1at pH 6.0, while the maximum adsorption capacity for the mixed Cr(VI) and Cu(II) system (qmixCr(VI)) was observed at pH 2.0 (0.38 mg·g−1). Comparing the adsorption behaviors and mechanisms, we found that kaolin prefers to adsorb hydrolyzed products of Cr(III) instead of Cr3+ion, while adsorption sites of kaolin surface were occupied primarily by Cu(II) through surface complexation, leading to Cu(II) inhibited Cr(VI) adsorption. Moreover, Cr(III) and Cr(VI) removal efficiency had a positive correlation with distribution coefficientKd. Cr(III) and Cr(VI) removal efficiency had a positive correlation with distribution coefficientKdand that of adsorption affinities of Cr(III) or Cr(VI) on kaolin was found to beKdCr(III) <KdCr(III)-Cu(II) andKdCr(VI) >KdCr(VI)-Cu(II).

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Section: Journal Of Chemistrymentioning

confidence: 99%

Section: Batch Adsorption Experimentsmentioning

confidence: 99%

Effects of Cu(II) on the Adsorption Behaviors of Cr(III) and Cr(VI) onto Kaolin

Liu

et al. 2016

Journal of Chemistry

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“…To better understand the adsorption mechanism, XPS measurement was carried out as shown in Figure 12. It can be seen that the Cr 2p1/2 and Cr 2p3/2 photoelectron peaks are located at 588.07 and 578.34 eV, respectively [36], which are assigned to the characteristic peaks of Cr(VI) and Cr(III), respectively. The results indicate that both Cr(VI) and Cr(III) are present on surface of tobermorite samples during the adsorption process.…”

Section: Resultsmentioning

confidence: 99%

“…The results indicate that both Cr(VI) and Cr(III) are present on surface of tobermorite samples during the adsorption process. Cr(VI) may be reduced to Cr(III) in the presence of organic matter [36,37] or at a pH of 2.0–6.0 in an acid environment through following redox reaction:HCrO 4 − + 7H + + 3e − → Cr 3+ + 4H 2 O…”

Section: Resultsmentioning

confidence: 99%

Synthesis, Characterization and Hexavalent Chromium Adsorption Characteristics of Aluminum- and Sucrose-Incorporated Tobermorite

Zhao

Wei

et al. 2017

Materials

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Tobermorites were synthesized from the lime-quartz slurries with incorporations of aluminum and sucrose under hydrothermal conditions, and then used for adsorption of Cr(VI). The chemical components, and structural and morphological properties of tobermorite were characterized by X-ray diffraction (XRD), thermogravimetric-differential scanning calorimetry (TG-DSC), Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), X-ray photoelectron spectroscopic (XPS) and N2 adsorption–desorption measurements. The formation and crystallinity of tobermorite could be largely enhanced by adding 2.3 wt.% aluminum hydroxide or 13.3 wt.% sucrose. Sucrose also played a significantly positive role in increasing the surface area. The adsorption performances for Cr(VI) were tested using a batch method taking into account the effects of pH, the adsorption kinetics, and the adsorption isotherms. The adsorption capacities of the aluminum- and sucrose-incorporated tobermorites reached up to 31.65 mg/g and 28.92 mg/g, respectively. Thus, the synthesized tobermorites showed good adsorption properties for removal of Cr(VI), making this material a promising candidate for efficient bulk wastewater treatment.

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“…Finally, the removal efficiency (R) was calculated according to the following equation Eq. (2) [34]:…”

Section: Ultrasonic-assisted Simultaneous Adsorption Experimentsmentioning

confidence: 99%

Highly efficient simultaneous ultrasonic-assisted adsorption of Pb(II), Cd(II), Ni(II) and Cu (II) ions from aqueous solutions by graphene oxide modified with 2,2′-dipyridylamine: Central composite design optimization

Zare‐Dorabei

Ferdowsi

Barzin

et al. 2016

Ultrasonics Sonochemistry

227

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In present work, a graphene oxide chemically modified with 2,2'-dipyridylamine (GO-DPA), was synthesized by simple, fast and low-cost process for the simultaneous adsorption of four toxic heavy metals, Pb(II), Cd(II), Ni(II) and Cu(II), from aqueous solutions. The synthesized adsorbent was characterized by FT-IR, XRD, XPS, SEM and AFM measurements. The effects of variables such as pH solution, initial ion concentrations, adsorbent dosage and sonicating time were investigated on adsorption efficiency by rotatable central composite design. The optimum conditions, specified as 8mg of adsorbent, 20mgL(-1) of each ion at pH 5 and short time of 4min led to the achievement of a high adsorption capacities. Ultrasonic power had important role in shortening the adsorption time of ions by enhancing the dispersion of adsorbent in solution. The adsorption kinetic studies and equilibrium isotherms for evaluating the mechanism of adsorption process showed a good fit to the pseudo-second order and Langmuir model, respectively. The maximum adsorption capacities (Qm) of this adsorbent were 369.749, 257.201, 180.893 and 358.824mgg(-1) for lead, cadmium, nickel and copper ions, respectively. The removal performance of adsorbent on the real wastewater samples also showed the feasibility of adsorbent for applying in industrial purposes.

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Efficient simultaneous removal of Cu(II) and Cr2O72− from aqueous solution by a renewable amphoteric functionalized mesoporous silica

Cited by 34 publications

References 54 publications

Effects of Cu(II) on the Adsorption Behaviors of Cr(III) and Cr(VI) onto Kaolin

Effects of Cu(II) on the Adsorption Behaviors of Cr(III) and Cr(VI) onto Kaolin

Synthesis, Characterization and Hexavalent Chromium Adsorption Characteristics of Aluminum- and Sucrose-Incorporated Tobermorite

Highly efficient simultaneous ultrasonic-assisted adsorption of Pb(II), Cd(II), Ni(II) and Cu (II) ions from aqueous solutions by graphene oxide modified with 2,2′-dipyridylamine: Central composite design optimization

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