Autonomous driving has become an important research area for road traffic, whereas testing of autonomous driving systems to ensure a safe and reliable operation, remains an open challenge. Substantial real-world testing or massive driving data collection does not scale, as the potential test scenarios in real-world traffic are infinite and covering large shares of them in test is impractical, thus critical ones have to be prioritized. In this study, we establish a systematic approach for critical test scenario identification with integrated tools and a workflow, to explore the most critical test scenarios and facilitate testing of the autonomous driving functions. We also demonstrate the effectiveness of our approach by using two real autonomous driving systems from the industry by collaborating with Volvo Cars. Our main contribution in this work is a feasible and complete tool-chain for critical test scenario identification that is general for testing different autonomous driving systems.