Efficient synthesis of highly soluble and functionalized fulleropyrrolidines

Parveen, Abdulrazack; Venkatesan, S.; Nagarajan, S.

doi:10.1039/c4ra15057k

Cited by 4 publications

(3 citation statements)

References 26 publications

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“…Molecular weight of the obtained samples of polystyrenes was determined by means of GPC (Fig. 42 These findings together with the lack of fullerene derivative elution peak in GPC analysis suggest that the obtained polystyrene contains small amount of chemically bound functionalized fullerenes. GPC chromatogram with retention volume acquired for polystyrene obtained in electropolymerization initiated by fullerene derivative III (Fig.…”

Section: Electropolymerization Of Styrenementioning

confidence: 81%

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Self-assembly of thioether functionalized fullerenes on gold and their activity in electropolymerization of styrene

et al. 2015

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A series of new fulleropyrrolidine alkylaromatic sulphides with different substituents on sulphur atom were synthesized. The redox properties of the C 60 derivatives in solution and self-assembled on gold electrode surfaces were characterized by cyclic and differential pulse voltammetry. All fullerene derivatives were found to be bound to the gold surface by the thioether sulphur anchoring group and not through fullerene sphere -Au surface interactions. The unique electrochemical properties of the synthesized fullerene derivatives allowed to show for the first time initiating activity of fullerene molecules in the anionic polymerization of styrene under electrochemical conditions.

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Section: Electropolymerization Of Styrenementioning

confidence: 81%

“…S26, ESI †), where bands at 526 and 1179 were observed. 42 These ndings together with Fig. 7 GPC analyses of (A) polystyrene obtained using fullerene thioether III, (B) products of electropolymerization without addition of fullerene derivative.…”

Section: Electropolymerization Of Styrenementioning

confidence: 99%

Self-assembly of thioether functionalized fullerenes on gold and their activity in electropolymerization of styrene

et al. 2015

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“…1) were synthesized by 1,3-dipolar cycloaddition of the in situ generated azomethine ylides to C 60 , by reaction of the corresponding alkyl and aryl substituted aldehyde with sarcosine and [C 60 ] fullerene by following the Prato's protocol [19,20].…”

Section: Resultsmentioning

confidence: 99%