Optically transparent
and highly conducting p-type Cu(I) incorporated
ZnS (Cu:ZnS) films are deposited by stacking individual layers of
CuS and ZnS using atomic layer deposition. The deposition chemistry
and growth mechanism are studied by in situ quartz crystal microbalance.
Compositional disorder in atomic scale is observed with increasing
Cu incorporation in the films that results in systematic decrease
in the optical transmittance in the visible spectrum. Again the conductivity
also emphatically depends on the volume fraction of phase-segregated
conducting covellite phase. An illustrious correlation prevailing
the interplay between the optical transparency and the charge transport
mechanism is established. The hole transport mechanism that indicates
insulator-to-metal transition with increasing Cu incorporation in
the composite is explained in terms of an inhomogeneously disordered
system. Under optimized conditions, the material having moderately
high optical transmission with degenerate carrier concentration lies
exactly at the confluence between the metallic and insulating regime.
The lowest resistivity that is obtained here (1.3 × 10–3 Ω cm) with >90% (after reflection correction) transmission
is highly comparable to the best ones that are reported in the field
and probably analogous to the commercially available n-type transparent
conductors.