Owing to the superior properties and stable operation, the Permanent Magnet Synchronous Motor (PMSM) is preferably used in wide industrial applications. But, the stability of motor is found to be dependent on its initial operating condition, showing the chaotic characteristic. Therefore, this paper addresses the chaos control of PMSM by developing four simple but effective controllers, which are mathematically designed by using the principle of Lyapunov’s method for asymptotic global stability. A comparative performance assessment has been carried out for the developed controllers in terms of settling time and peak over shoot. Furthermore, the concept of conventional proportional-integration type controller has been extended to develop two more controllers for chaos control of PMSM. Numerical simulation has been carried out in Matlab environment for performance evaluation of developed controllers. The obtained analytical results have been validated through experimental implementation in real time environment on Multisim/Ultiboard platform.