Angewandte Chemie
 1998
DOI: 10.1002/(sici)1521-3757(19980420)110:8<1152::aid-ange1152>3.0.co;2-o
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Ein neuer Tetracyclus durch Dimerisierung desN-Methylpyridazinium-Ions in wäßriger Lösung

Charles R. Clark
1
,
Allan G. Blackman
2
,
Akbar Mobinikhaledi
3
et al.

Abstract: In einer Eintopfsynthese bei Raumtemperatur dimerisiert das N‐Methylpyridazinium‐Ion 1 in einer Folge von OH−‐katalysierten Prozessen stereospezifisch und mit 100% Umsatz zum neuen Tetraazafluoren 2. Vier der Einzelschritte lassen sich 1H‐NMR‐spektroskopisch direkt nachweisen und verfolgen.

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