Einander durchdringende Netze: geordnete, periodische Verschlingung

Batten, Stuart Robert; Robson, Richard

doi:10.1002/(sici)1521-3757(19980605)110:11<1558::aid-ange1558>3.0.co;2-7

Angewandte Chemie

1998

DOI: 10.1002/(sici)1521-3757(19980605)110:11<1558::aid-ange1558>3.0.co;2-7

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Einander durchdringende Netze: geordnete, periodische Verschlingung

Stuart Robert Batten

Richard Robson

Abstract: Unauflöslich ineinander verwoben sind in vielen Festkörperstrukturen von polymeren, über H‐Brücken gebundenen Netzen und von Koordinationspolymeren die als voneinander unabhängig betrachteten ein‐, zwei‐ oder gar dreidimensionalen Netzstrukturen. Rechts ist z. B. die gegenseitige Durchdringung der Adamantaneinheiten zweier diamantartiger Netze gezeigt. Aus der detaillierten Beschreibung und Systematik der mehrfachen gegenseitigen Durchdringung von derartigen Netzen in Festkörperstrukturen lassen sich unter and… Show more

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Cited by 463 publications

References 250 publications

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1D- and 2D-Coordination Polymers from Self-Complementary Building Blocks: Co-Crystallization of (P)- and (M)-Single-Stranded Diastereoisomers

Saalfrank¹,

Maid

Hampel

et al. 1999

Eur. J. Inorg. Chem.

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Reaction of methanolic copper(II) acetate solution with oxazolidine 21 (HL7) led to the formation of the one‐dimensional coordination polymer 1D‐∞1[CuL27] 23. On the contrary, reaction of copper(II) acetate in methanol with pyrrolidine 24 (HL8) yielded the two‐dimensional coordination polymer 2D‐∞2[CuL28] 26. A common feature of 23 and 26 are the C2h‐symmetric coordinatively unsaturated building blocks 22 and 25. In 1D‐∞1[CuL27] 23, the cyano groups are linked to copper in a side‐on fashion and the monomers 22 are oriented parallel to one another, whereas in 2D‐∞2[CuL28] 26 the cyano groups are bound to copper in the end‐on mode and the monomers 25 are oriented at an angle of 117° to one another. In both 1D‐23 and 2D‐26, copper has a distorted octahedral coordination sphere. On the other hand, reaction of methanolic copper(II) acetate solution with enantiomerically pure (5S)‐pyrrolidine 27 (HL9(S)) led to the formation of the diastereomeric helical strands (M)‐/(P)‐1D‐∞1[CuL29] 29. (M)‐ and (P)‐29 are present in pairs in the infinite unit cell. In helical 1D‐29, copper is tetragonal‐pyramidally coordinated and the C2‐symmetric monomers 28 (CuL29) are linked through only one cyano group. Moreover, it has been shown that the reaction of chiral racemic pyrrolidine 30 (HL10(R,S)) with copper(II) acetate via the intermediate Ci‐symmetric building blocks 31 (CuL10(R)L10(S)) furnishes one‐dimensional 1D‐∞1[CuL10(R)L10(S)] 32. Single‐crystal X‐ray diffraction analyses of the supramolecular species 23, 26, 29, and 32 unequivocally establish the structures of these coordination polymers.

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1D- and 2D-Coordination Polymers from Self-Complementary Building Blocks: Co-Crystallization of (P)- and (M)-Single-Stranded Diastereoisomers

Saalfrank¹,

Maid

Hampel

et al. 1999

Eur. J. Inorg. Chem.

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Two Examples of Novel and Unusual Double-Layered, Two-Dimensional CuII Compounds with Bridging 1,3-Bis(1,2,4-triazol-1-yl)propane

Albada

Guijt

Haasnoot

et al. 2000

Eur. J. Inorg. Chem.

124

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Substituent-Dependent Formation of Supramolecular Aggregates of 6-Hydroxy-trans-3-hexenoic Acids in the Solid State

Strauch

Rinderknecht

Erker³

et al. 2000

Eur. J. Org. Chem.

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Einander durchdringende Netze: geordnete, periodische Verschlingung

Cited by 463 publications

References 250 publications

1D- and 2D-Coordination Polymers from Self-Complementary Building Blocks: Co-Crystallization of (P)- and (M)-Single-Stranded Diastereoisomers

1D- and 2D-Coordination Polymers from Self-Complementary Building Blocks: Co-Crystallization of (P)- and (M)-Single-Stranded Diastereoisomers

Two Examples of Novel and Unusual Double-Layered, Two-Dimensional CuII Compounds with Bridging 1,3-Bis(1,2,4-triazol-1-yl)propane

Substituent-Dependent Formation of Supramolecular Aggregates of 6-Hydroxy-trans-3-hexenoic Acids in the Solid State

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