This is partly an expository paper, where the authors' work on pseudoriemannian Einstein metrics on nilpotent Lie groups is reviewed. A new criterion is given for the existence of a diagonal Einstein metric on a nice nilpotent Lie group. Classifications of special classes of Ricci-flat metrics on nilpotent Lie groups of dimension ≤ 8 are obtained. Some related open questions are presented. MSC 2010 : 53C25; 53C50, 53C30, 22E25.