“…This report motivated us to formulate Rigid Ion Model (RIM) to describe the thermal properties of La 1Àx Ca x MnO 3 compounds. Earlier we have used the RIM model successfully to study the thermal properties of some perovskite manganites and other inorganic compounds over a fairly wide range of temperatures [5][6][7][8][9]. As the electronic and magnetic phase diagram of La 1Àx Ca x MnO 3 is well established for all the values of concentration (x) [10], the main focus of the present paper is to explore temperature dependence of the lattice specific heat of La 1Àx Ca x MnO 3 in different regions of its phase diagram (x ¼ 0.125, 0.175, 0.25, 0.35, 0.50, 0.67 and 0.75).…”