Heat-bodied oils were prepared by
thermal treatment of soybean
oil under inert atmosphere. Different viscosity grades of heat-bodied
oils synthesized by varying the reaction time were investigated for
various properties including viscosity, viscosity index, elastohydrodynamic
film thickness, and pressure–viscosity coefficient. Heat-bodied
oils displayed elastohydrodynamic film thickness characteristics typical
of lubricating oils. The film thickness of heat-bodied oils increased
with increasing entrainment speed and viscosity, decreased with increasing
temperature, and was unchanged with varying load. Pressure–viscosity
coefficients of heat-bodied oils were estimated from film thickness
as well as from physical property data. The pressure–viscosity
coefficient values of heat-bodied oils increased with increasing viscosity
and decreasing temperature and were in the range displayed by such
oils as polyol esters, poly-α-olefins, and petroleum-based base
oils. Heat-bodied oils provide access to a wide viscosity range of
biobased oils not attainable with vegetable oils, without serious
negative impact on critical lubricant properties such as viscosity
index, film thickness, and pressure–viscosity coefficient.