“…Carbon-based materials and metallic fillers such as graphite [5], graphite/graphene nanoplateles (GNPs) [6,7], graphene [8], carbon nanotubes (CNTs) [9], carbon fiber [10,11], silver particles, silver nanowires [12], and copper nanowires [2,13] have been widely utilized to fabricate polymer-based TIMs owing to their extraordinary inherent thermal conductivity [14,15]. However, the incorporation of electrically conductive fillers will inevitably cause the great deterioration of electrical insulation performance, which hinders the wide use of these TIMs in next-generation microelectronics devices [16,17] such as LED devices with chips directly placing on the heat sink, single chip packages [18], and high-voltage devices.…”