Improving the conductivity of the lubricant itself is the main idea behind current conductive lubricant designs. However, as per previous studies, the interface state has a more dominant influence on the interface conductivity than the conductivity of the lubricant. Therefore, improving the interface state is a more direct and effective way to improve the interface conductivity. In this study, improving the interface state is the primary idea underlying the design of a conductive lubricant. Graphene/ionic liquid composites (MG/IL) with excellent interfacial adsorption properties are prepared using ionic liquid non‐covalently modified graphene. Subsequently, corresponding conductive greases are synthesized using multilayer graphene, ionic liquid, and MG/IL as additives. The lubricating and conductive properties of these greases are characterized by performing current‐carrying friction tests. The results show that when MG/IL is used as an additive, the grease exhibits excellent lubricating performance and the lowest average contact resistance. This finding is primarily attributed to the multilayer graphene and ionic liquid in MG/IL acting synergistically to improve the interface state significantly, which decreases the contact resistance and increases the conductivity of the friction interface. This work provides a novel idea for the design of conductive lubricants.This article is protected by copyright. All rights reserved.