Low-dielectric-constant amorphous fluorinated carbon (a-C:F) films were prepared using plasma-enhanced chemical vapor deposition (PECVD) from C 4 F 6 (hexafluoro-1,3-butadiene) gas, which is expected to be a substitutional gas owing to its low global warming potential (GWP). Kinetic analysis revealed that the density of C 4 F 6 in plasma has a proportional relation to film growth rate, which suggests that C 4 F 6 is a main deposition precursor. From our previous study, this density affects the C-CF bond ratio in the film. In this study, we studied the effect of C-CF bond ratio on the thermal stability of the films by examining residual film thickness after vacuum annealing. A higher C-CF bond ratio resulted in a higher thermal stability, but the film became leaky after 300 C annealing.