The aim of this chapter is to review the current state of knowledge in ionic materials with crystallite dimensions less than 100 nm, systems which sometimes are referred to as nanoionics. The chapter will detail the preparation, characterization and the important applications of these materials, especially in sensors, solid-state batteries, and fuel cells. Particular focus will be placed on ionic transport in these materials, as this is a topic of considerable contemporary interest, and where conflicting reports exist of enhanced diffusion in nanocrystals.
IntroductionNanomaterials are systems that contain particles with one dimension in the nanometer regime. The past decade has witnessed a growing intense interest from biologists, chemists, physicists, and engineers in the application of these materialsthe so-called nanotechnology, which is sometimes referred to as the next industrial revolution [1]. The reasons for such interest are the unusual properties and potential technological applications that are exhibited by these materials when compared to their bulk counterparts [2][3][4][5][6][7][8][9][10]. In this chapter, attention will be focused on rather simple ionic solids, where the interatomic attractions are predominantly coulombic forces, and the dimensions are predominantly <100 nm. Such systems have been termed nanoionics [11,12].There are three dominant reasons for the study of these particular systems:. The simplicity of the interatomic forces means that some of the generic features and problems of nanomaterials should be tractable to theoretical and/or computer modeling approaches for these particular systems. . Many relatively simple ionic compounds, such as binary halides and oxides, in their bulk form have important technological applications as electrolytes, catalysts, Solid State Electrochemistry I: Fundamentals, Materials and their Applications. Edited by Vladislav V. Kharton