To
recover the low-grade waste heat (300–500 K), it is of urgent
importance to develop and improve the thermoelectric performance at
a low-temperature region. Herein, we have realized a record high ZT value of 1.4 at 410 K and a record high average ZT value of 0.6 in the temperature interval from 300 to
400 K for Sb-doped Ag2Sb
x
Te1–x
(x = 0–0.03)
compounds, which show an improvement of 180 and 120% compared to pristine
Ag2Te, respectively. Sb doping increases the carrier concentration
and electrical conductivity, leading to a remarkable improvement of
electrical transport properties. The Ag2Sb0.015Te0.985 sample obtains the maximal power factor of 1.07
× 10–3 W m–1 K–2 at 410 K, which is increased by 80% in comparison to that of pristine
Ag2Te. Moreover, as a result of the intensified alloying
phonon scattering by Sb doping, Ag2Sb0.01Te0.99 possesses the minimum lattice thermal conductivity of
0.35 W m–1 K–1 at 300 K, which
demonstrates a decline of 57% compared to that of pristine Ag2Te. All of these produce a great enhancement on the thermoelectric
performance of Ag2Te materials, which shows great potential
in the application of recycling the low-grade waste heat at a low-temperature
region.