Abstract:We report on the electrical properties of thin film transistors based on zinc oxide (ZnO) layers grown by low temperature (100–170°C) atomic layer deposition. As evidenced through Hall effect measurements, a drastic decrease of the carrier concentration occurred for ZnO films grown at 100°C. Time of flight–secondary ions mass spectroscopy analysis revealed that this decrease is associated with an increase of the hydroxide groups in the ZnO layer which suppressed oxygen vacancy formation. Transistors fabricated… Show more
“…42,43 Therefore, the expected limiting value for D n will be 7 cm 2 s -1 . The maximum value here, D n ) 0.4 cm 2 /s -1 , suggests that diffusion is still limited by traps and thus that the Fermi level has not reached the conduction band.…”
Dye-sensitized solar cells based on ordered arrays of polycrystalline ZnO nanotubes, 64 µm in length, are shown to exhibit efficient electron collection over the entire photoanode array length. Electrochemical impedance spectroscopy, open-circuit photovoltage decay analysis, and incident-photon-to-current efficiency spectra are used to quantify charge transport and lifetimes. Despite the relatively thick photoanode, the charge extraction time is found to be faster than observed in traditional TiO 2 nanoparticle photoanodes. If the extraction dynamics are interpreted as diffusive, effective electron diffusion coefficients of up to 0.4 cm 2 s -1 are obtained, making these pseudo-1D photoanodes the fastest reported for an operating DSC to date. Rapid electron collection is of practical significance because it should enable alternative redox shuttles, which display relatively fast electron-interception dynamics, to be employed without significant loss of photocurrent.
“…42,43 Therefore, the expected limiting value for D n will be 7 cm 2 s -1 . The maximum value here, D n ) 0.4 cm 2 /s -1 , suggests that diffusion is still limited by traps and thus that the Fermi level has not reached the conduction band.…”
Dye-sensitized solar cells based on ordered arrays of polycrystalline ZnO nanotubes, 64 µm in length, are shown to exhibit efficient electron collection over the entire photoanode array length. Electrochemical impedance spectroscopy, open-circuit photovoltage decay analysis, and incident-photon-to-current efficiency spectra are used to quantify charge transport and lifetimes. Despite the relatively thick photoanode, the charge extraction time is found to be faster than observed in traditional TiO 2 nanoparticle photoanodes. If the extraction dynamics are interpreted as diffusive, effective electron diffusion coefficients of up to 0.4 cm 2 s -1 are obtained, making these pseudo-1D photoanodes the fastest reported for an operating DSC to date. Rapid electron collection is of practical significance because it should enable alternative redox shuttles, which display relatively fast electron-interception dynamics, to be employed without significant loss of photocurrent.
“…9 Mridha and Basak 10 showed that a structure based on ZnO/PANI reveals a rectifying behavior suitable for fabricating UV photodetectors. Atomic layer deposition ͑ALD͒ of ZnO provides the advantages of ͑i͒ producing uniform polycrystalline layers under low-temperature conditions without involving high energy processes, with optimum electrical properties 11 and ͑ii͒ allowing atomic layer control of thickness and composition, due to the surface limited reaction of the precursors. 12 The low growth temperature allows growing the inorganic material on top of the organic.…”
“…1 The tunable conductivity of ZnO thin film makes it a very promising candidate for both passive and active electronic applications. [2][3][4] Although zinc oxide TFTs with good field-effect mobility have been reported using various deposition techniques, [5][6][7][8][9][10] the stability of ZnO and other oxide-based TFTs under gatebias stress is a major concern for display applications. [11][12][13][14] Further, the increased temperature of display devices due to prolonged use or operation under harsh conditions can significantly shift the threshold voltage of the pixel-TFTs, 14,15 which would affect the performance of the corresponding device.…”
We report highly stable gate-bias stress performance of thin film transistors (TFTs) using zinc oxide (ZnO)/hafnium oxide (HfO2) multilayer structure as the channel layer. Positive and negative gate-bias stress stability of the TFTs was measured at room temperature and at 60 °C. A tremendous improvement in gate-bias stress stability was obtained in case of the TFT with multiple layers of ZnO embedded between HfO2 layers compared to the TFT with a single layer of ZnO as the semiconductor. The ultra-thin HfO2 layers act as passivation layers, which prevent the adsorption of oxygen and water molecules in the ZnO layer and hence significantly improve the gate-bias stress stability of ZnO TFTs.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.