“…Due to these size effects the conductivity of the samples of 4 and 3 nm is smaller. Moreover, it is seen that the value of the activation energy for the grain size of 5 nm is found to be 0.31 eV, which indicates that below 5 nm the conduction process is due to the holes, i.e., ferrites formed are p-type semiconductors [22,23], as a result the value of activation energy are also found to increase on the basis of Verwey conduction mechanism [24]. The scattering due to the grain boundary dominates; in addition to electrical resistivity and the temperature coefficient of materials are increased if the size of the crystallite is smaller than the electron mean free path.…”