The on-demand generation and separation of entangled photon pairs are key components of quantum information processing in quantum optics [1][2][3] . In an electronic analogue, the decomposition of electron pairs represents an essential building block for using the quantum state of ballistic electrons in electron quantum optics [4][5][6][7] . The scattering of electrons has been used to probe the particle statistics of stochastic sources in Hanbury Brown and Twiss experiments 8,9 and the recent advent of on-demand sources further offers the possibility to achieve indistinguishability between multiple sources in Hong-Ou-Mandel experiments [10][11][12][13][14][15] . Cooper pairs impinging stochastically at a mesoscopic beamsplitter have been successfully partitioned, as verified by measuring the coincidence of arrival [16][17][18][19][20][21] . Here, we demonstrate the splitting of electron pairs generated on demand. Coincidence correlation measurements allow the reconstruction of the full counting statistics, revealing regimes of statistically independent, distinguishable or correlated partitioning, and have been envisioned as a source of information on the quantum state of the electron pair [22][23][24][25][26] . The high pair-splitting fidelity opens a path to future on-demand generation of spin-entangled electron pairs from a suitably prepared two-electron quantum-dot ground state.The few-electron source is based on a single-parameter non-adiabatic quantized charge pump [27][28][29] , which enables the deterministic generation of single electrons and electron pairs with tunable emission energy 12,30 . Non-equilibrium electrons propagate along the edge of a quantum Hall sample with minimal inelastic scattering. The device and measurement set-up are presented in Fig. 1. An energy-selective detector barrier splits the incoming beam of electrons into two detector paths. The coincidence of arrival of electrons in the two detector channels leads to positive correlation between the time-dependent current signals. These correlations are inferred from a measurement of the zero-frequency cross-correlation shot noise. Although an oscillator-controlled electron source is noiseless 31 , the splitting of electron pairs generates partitioning noise and enables tomography of the probability distribution for the partitioning outcomes within each emission cycle.The generation and energy-selective detection of on-demand non-equilibrium electrons was demonstrated with the electron source configured to emit one electron with charge e and repetition frequency f of 280 MHz. Figure 2 shows the transmitted current I T as a function of barrier energy. The maximum level of I T is 2% below the emission current I P = 1 ef due to residual inelastic scattering events on the 2-µm-long path to the barrier (the emission error of the source is <1 × 10
−4). For energies greater than 57 meV, the current is pinched off as all of the emitted electrons are reflected at the beamsplitter. The emission energy is defined by the exit barrier height and ca...