We have investigated spin-electricity conversion on surface states of bulk-insulating topological insulator (TI) materials using a spin pumping technique. The sample structure is Ni-Fe|Cu|TI trilayers, in which magnetic proximity effects on the TI surfaces are negligibly small owing to the inserted Cu layer. Voltage signals produced by the spin-electricity conversion are clearly observed, and enhanced with decreasing temperature in line with the dominated surface transport at lower temperatures. The efficiency of the spin-electricity conversion is greater for TI samples with higher resistivity of bulk states and longer mean free path of surface states, consistent with the surface spin-electricity conversion.Injection and detection of non-equilibrium spins are key techniques in the field of spintronics [1]. A powerful method to inject spins is spin pumping. Spin pumping enables dynamical spin injection from a ferromagnet into an adjacent non-magnetic metal, which is induced by coherent precession of magnetization at ferromagnetic resonance (FMR) [2]. In spin pumping experiments, bilayers comprising ferromagnetic Ni 81 Fe 19 (permalloy, Py) and nonmagnetic Pt have been studied as a typical system [2-6]. Though Pt has been widely used for spin detection owing to its strong spin-orbit interaction, search of more efficient spin detectors is one of the urgent issues in the spintronics field [7,8].A topological insulator (TI) is a promising material for spintronics application because of its potential for highly efficient spin-electricity conversion [9,10]. Topological insulators are a state of quantum matter [11][12][13], in which the surface is metallic, while the interior is insulating. Spin-electricity conversion on TI materials has recently been investigated using spin pumping for bulk-metallic samples (Bi 2 Se 3 ) [14][15][16] and also for bulk-insulating ones [17]. In a previous report [17], some authors of the present paper demonstrated the spinelectricity conversion induced by spin pumping into surface states of TIs, Bi 1.5 Sb 0.5 Te 1.7 Se 1.3 (BSTS) [18,19] and Sn-doped Bi 2 Te 2 Se (SnBTS) [20] in contact with Py. Since millimeter-thick TI samples were used in [17], the inverse spin Hall signal from bulk carriers are neglected and the observed spin-electricity conversion signal was safely ascribed to a surface contribution. The sign of * K. T. Yamamoto and Y. Shiomi contributed equally to this work.† Corresponding author; Electronic address: shiomi@imr.tohoku.ac.jp the generated electric signals is consistent with the spinelectricity conversion on the topological surface state, whereas the opposite sign is expected for co-existing Rashba surface states [21]. On the surface states of TIs, since spin direction and electron-flow direction have oneto-one correspondence (the spin-momentum locking), injected spins are converted into electric currents along an in-plane direction on the surface, when the bulk state is sufficiently insulating. Although highly efficient spinelectricity conversion has been reported fo...