The electrical conductivity, the thermoelectric power and the magnetic susceptibility of molten Tl + CuTlSe2 mixtures have been measured up to 950°C. These mixtures exhibit a sharp decrease in electrical conductivity and a change in sign of thermoelectric power around the stoichiometric composition CuTl3Se2. Measurements of magnetic susceptibility also indicate a marked anomaly at this composition. These electronic properties for molten Tl + CuTlSe2 mixtures are discussed in the light of current transport theories employed in the amorphous and liquid semiconductors.