Electrical resistivity of solutions of barium in liquid sodium

Addison, C. C.; Creffield, Geoffrey K.; Hubberstey, Peter; Pulham, R. J.

doi:10.1039/j19710001393

J. Chem. Soc., A

1971

DOI: 10.1039/j19710001393

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Electrical resistivity of solutions of barium in liquid sodium

C. C. Addison¹,

Geoffrey K. Creffield²,

Peter Hubberstey³

et al.

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Cited by 12 publications

(2 citation statements)

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“…Consequently, we chose the dilute region for detailed investigation. A further impetus for studying the properties of dilute solutions was provided by our continuing interest (6)(7)(8)(9)(10)(11) in the nature of solutes dissolved in liquid metals at concentrations where interactions between the solute atoms are less important than those between the solute and solvent.…”

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Thermodynamic Properties of Solutions of Group IV Metals Dissolved in Liquid Sodium

Hubberstey¹,

Castleman²

1972

J. Electrochem. Soc.

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An emf cell technique was used to measure the thermodynamic properties of Pb-Na solutions at temperatures ranging from 245 ~ to 500~ and compositions between 2.35 and 16.79 atomic per cent (a/o) Pb. The results, while in general agreement with earlier work, reveal that the deviations from ideal solution behavior cross over from negative to positive at low Pb concentrations. This property has not been previously reported for the Pb-Na system. Sodium activity measurements, which were made as a function of decreasing temperature, display a marked change in slope upon transition to a two-phase region. The resulting liquidus-line is in agreement with the published phase diagram. A study of the change in sodium activity as a function of temperature was also made for saturated solutions of Ge in Na. The results show that the solubility of Ge in Na is represented by the equation

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Thermodynamic Properties of Solutions of Group IV Metals Dissolved in Liquid Sodium

Hubberstey¹,

Castleman²

1972

J. Electrochem. Soc.

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“…A similar phenomenon about resistivity saturation also reported on solutions of barium to liquid sodium. 21) The saturated value indicated that the alloying process of Ga-Na was completed. If the alloying process caused Ga atoms to be isolated in the Ga-Na melt, this would lead to an increase of N 2 solubility in flux.…”

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Monitoring of Ga-Na melt electrical resistance and its correlation with crystal growth on the Na Flux method

Tandryo

Murakami

Kitamura

et al. 2019

Appl. Phys. Express

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The electrical resistance of Ga-Na melt used for gallium nitride crystal growth on a Na flux was investigated with the four-point probe method. Electrical resistance of melt was measured isothermal at 870 °C as the function of time. Pressure decay measurement and crystal growth evaluation were performed and show that the electrical resistance of melt and the number of dissolved nitrogen were strongly correlated. Time-dependency of nitrogen concentration in melt was revealed and verified from the increasing growth rate. The strong correlation between measurement and crystal growth shows the high potential use of electrical resistance measurements as the monitoring method.

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Solutions of aluminum in liquid lithium: contribution to the Li-Al phase diagram

Pulham

Hubberstey

Hemptenmacher

1994

JPE

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Electrical resistivity of solutions of barium in liquid sodium

Cited by 12 publications

References 0 publications

Thermodynamic Properties of Solutions of Group IV Metals Dissolved in Liquid Sodium

Thermodynamic Properties of Solutions of Group IV Metals Dissolved in Liquid Sodium

Monitoring of Ga-Na melt electrical resistance and its correlation with crystal growth on the Na Flux method

Solutions of aluminum in liquid lithium: contribution to the Li-Al phase diagram

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