Electro-induced O–S bonding reaction targeting biological macromolecules

Jiang, Shuqiang; Xiao, Longyu; Pan, Li; Huang, Qiaoyu; Huo, Fujin; Gao, Meng; Lu, Cuifen; Wu, Pan; Weng, Yue

doi:10.1039/d3qo01794j

Org. Chem. Front.

2024

DOI: 10.1039/d3qo01794j

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Electro-induced O–S bonding reaction targeting biological macromolecules

Shuqiang Jiang,

Longyu Xiao,

Li Pan

et al.

Abstract: This study endeavors to explore the utilization of aromatic sulfinates as bioconjugation handles, addressing the challenges associated with the modification of aromatic amino acid residues (Tyrosine) and paving the way...

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Cited by 2 publications

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Synergistic Photoredox and Electrochemical Catalysis in Organic Synthesis and Late‐Stage Functionalizations

Sun,

Lin,

Chen

et al. 2024

ChemCatChem

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This review delves into the innovative field of interfacial photoelectrochemical (iPEC) and photoelectrochemical (PEC) catalysis, the dynamic synthesis methodologies that seamlessly integrates electrochemical and photoredox catalysis for efficient and environmentally friendly reactions. Utilizing minute quantities of photocatalysts, visible light becomes a powerful tool, generating transient excited states to catalyze a spectrum of reactions through single‐electron oxidation or reduction events. The review categorizes recent advancements, highlighting applications in organic synthesis, late‐stage modifications, and the distinctive features of photoelectrochemical methodology. Despite being in its early stages, this synergistic approach holds great promise for propelling organic synthesis forward, with potential applications in large‐scale synthesis and diverse late‐stage functionalizations, including asymmetric catalysis and bioconjugation strategies for biomolecule modifications.

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Synergistic Photoredox and Electrochemical Catalysis in Organic Synthesis and Late‐Stage Functionalizations

Sun,

Lin,

Chen

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

show abstract

Electrochemical diversification of cysteine derivatives and cysteine-containing peptides to phosphorothioates and sulfinates

Xiao,

Li,

Huang

et al. 2024

Org. Chem. Front.

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Electro-induced O–S bonding reaction targeting biological macromolecules

Abstract: This study endeavors to explore the utilization of aromatic sulfinates as bioconjugation handles, addressing the challenges associated with the modification of aromatic amino acid residues (Tyrosine) and paving the way...

Cited by 2 publications

References 48 publications

Synergistic Photoredox and Electrochemical Catalysis in Organic Synthesis and Late‐Stage Functionalizations

Synergistic Photoredox and Electrochemical Catalysis in Organic Synthesis and Late‐Stage Functionalizations

Electrochemical diversification of cysteine derivatives and cysteine-containing peptides to phosphorothioates and sulfinates

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