Electro optic Kerr effect studies of polar-polar binary liquid mixtures

Comparative Dielectric Study and Molecular Interactions of Binary Mixtures of (Cyclohexanone + 1-Alkanols) and (Cyclopentanone or Cyclohexanone + Cyclohexanol or Cyclohexane) atT= 298.15 K

“…Studies of the dielectric properties of liquid mixtures at static and optical frequencies are important and desirable for achieving a theoretical and practical understanding of the nature of intermolecular forces and their resulting structures in the mixture. − Many experiments have been carried out to investigate the static dielectric permittivity and other physical and physicochemical behavior of binary mixtures; − however, reliable experimental data over a wide range of compositions for different liquid mixtures are still important and required. Among the many binary mixtures that have been investigated, hydrogen-bonded systems such as ketone–alcohol are of particular interest. − …”

Dielectric study of molecular association in the binary mixtures (2-ethyl-1-hexanol+alcohol) and (cyclohexane+alcohol) at 298.2 K

“…Therefore, the solution chemistry of these compounds can be strongly influenced by the aggregation phenomena, which can play an important role in the physical properties of these polar molecules. The molecular association of alcohols through intermolecular hydrogen bonding has been the subject of considerable interest in recent years [9,10]. The dielectric study of a number of alcohol solutions in non-polar and polar solvents have been carried out by Durov [11,12].…”

“…The dielectric study of a number of alcohol solutions in non-polar and polar solvents have been carried out by Durov [11,12]. Rajagopal et al [9] have reported the variation of dipole moment values with mole fraction for some liquid mixtures such as (methanol + acetone) binary mixtures.…”

Relative permittivity data of binary mixtures containing 2-butanol, 2-butanone, and cyclohexane

“…Due to the presence of the -OH group in the molecule, the solution chemistry of these compounds can be strongly influenced by the intermolecular hydrogen bond formation, which can play an important role in the physical properties of these molecules. Therefore, they have been subject of extensive practical and theoretical investigations to study intermolecular hydrogen bonding [14][15][16][17][18]. The aliphatic alcohols are excellent H-bond donors/ acceptors, and therefore, are strongly associated through intermolecular H-bonding.…”

“…On the other hand, ketones are an important class of industrial chemicals with many scientific and industrial applications [14]. These compounds with a carbonyl group (C@O) are strongly hydrogen-bond acceptors.…”