Electro-optical and electrochemical properties of an conjugated cyclopolymer: Poly(9,9-dipropargylfluorene)

Gal, Yeong‐Soon; Jin, Sung‐Ho; Hyun, Ae-Ran; Park, Young‐Il; Park, Jong‐Wook; Lim, Kwon Taek; Lee, Won‐Chul

doi:10.1016/j.jiec.2008.02.001

Cited by 10 publications

(3 citation statements)

References 30 publications

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“…Fluorene is another compound that has interesting electro‐ and optical properties. Fluorene‐containing poly(phenylene vinylene) moieties are good candidates for light‐emitting devices and other purposes 15…”

Section: Introductionmentioning

confidence: 99%

Diol‐Linked Microporous Networks of Cubic Siloxane Cages

Wada¹,

Iyoki²,

Sugawara‐Narutaki³

et al. 2012

Chemistry A European J

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A new class of inorganic-organic hybrid porous materials has been synthesized by a reaction between octa(hydridosilsesquioxane) (H(8)Si(8)O(12)), which has a double-four-ring (D4R) structure, and various diols, such as 1,3-propanediol (PD), 1,4-cyclohexanediol (CHD), and 1,3-adamantanediol (AD). Solid-state (29) Si magic-angle-spinning NMR spectroscopic analysis confirmed that most of the corner Si-H groups reacted with diols to form Si-O-C bonds with retention of the D4R cage. Nitrogen adsorption-desorption studies showed that the products are microporous solids with high BET surface areas (up to ≈580 m(2) g(-1) for CHD- and AD-linked products). If n-alkanediols are used as linkers, the surface area becomes smaller as the number of carbon atoms is increased. The thermal and hydrolytic stability of the products strongly depend on the type of diol linkers. The highest stabilities are found for the AD-linked products, which are thermally stable up to around 400 °C and remain intact even after being soaked in water for 1 day. In contrast, the PD-linked product is easily hydrolyzed in water to give microporous silica. These results offer a new route toward a series of silica-based porous materials with unique structures and properties.

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Section: Introductionmentioning

confidence: 99%

Diol‐Linked Microporous Networks of Cubic Siloxane Cages

Wada¹,

Iyoki²,

Sugawara‐Narutaki³

et al. 2012

Chemistry A European J

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“…Various types of conjugated polymers such as polyacetylenes, poly(pyrrole)s, poly(thiophene)s, poly(phenylenevinylene)s, and poly (9,9-dialkylfluorene)s were designed and prepared [1][2][3][4][5][6][7][8][9][10]. As a sequence, these conjugated polymers are expected to show unique properties such as electrical conductivity, paramagnetism, migration and transfer of energy, color, photo-and electroluminescences, chemical reactivity and complex formation ability, and so on [1,[11][12][13][14][15][16].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and properties of poly(N-benzoyl-2-ethynylpyridinium chloride)

Gal¹,

Jin²,

Park³

et al. 2011

Journal of Industrial and Engineering Chemistry

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“…We had firstly used this catalyst for the cyclopolymerization of nonconjugated diyne monomers [25]. Unlike the polymerization behaviors of DEDPM by using Mo-based catalysts, which the polymerization proceeded rapidly in initial reaction stage [21,23], the polymerization of DEDPM by (NBD)PdCl 2 catalyst proceeded in mild homogeneous manner to give the moderate yield of polymer (56%).…”

Section: Resultsmentioning

confidence: 99%

Electro‐Optical and Electrochemical Properties of a Conjugated Polymer Prepared by the Cyclopolymerization of Diethyl Dipropargylmalonate

Gal

Lee

Lyoo

et al. 2008

International Journal of Photoenergy

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The electro-optical and electrochemical properties of poly(diethyl dipropargylmalonate) were measured and discussed. Poly(diethyl dipropargylmalonate) prepared by (NBD)PdCl 2 catalyst was used for study. The chemical structure of poly(diethyl dipropargylmalonate) was characterized by such instrumental methods as NMR ( 1 H-, 13 C-), IR, and UV-visible spectroscopies to have the conjugated cyclopolymer backbone system. The microstructure analysis of polymer revealed that this polymer have the six-membered ring moieties majorly. The photoluminescence peak of polymer was observed at 543 nm, which is corresponded to the photon energy of 2.51 eV. The cyclovoltamograms of the polymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. It was found that the kinetics of the redox process of this conjugated cyclopolymer might be controlled by the diffusion-control process from the experiment of the oxidation current density of polymer versus the scan rate.

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Electro-optical and electrochemical properties of an conjugated cyclopolymer: Poly(9,9-dipropargylfluorene)

Cited by 10 publications

References 30 publications

Diol‐Linked Microporous Networks of Cubic Siloxane Cages

Diol‐Linked Microporous Networks of Cubic Siloxane Cages

Synthesis and properties of poly(N-benzoyl-2-ethynylpyridinium chloride)

Electro‐Optical and Electrochemical Properties of a Conjugated Polymer Prepared by the Cyclopolymerization of Diethyl Dipropargylmalonate

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