“…1–3 They thus possess unique optical and electronic properties, such as strong absorption in the visible–near infrared region, namely the Q band (>670 nm, ε > 1 × 10 5 M −1 cm −1 ), and high electrical conductivity, which enable them to be used in various fields, including as dyes and pigments, phototherapeutic agents, semi-conductors, non-linear optics, and catalysis. 4–13 These properties are generally tuned by modifying them with peripheral or axial substituents as well as changing central chelated ions. 3,5,14–19 For example, the introduction of electron-donating groups at the peripheral position of macroclycles of Pcs (especially at the α-position) red-shifts the absorption of their Q bands relative to that of unsubstituted Pcs.…”