Electro-oxidative quinylation of sulfides to sulfur ylides in batch and continuous flow

Huang, Xiangxing; Yao, Yifei; Yin, Xing; Guan, Wenjing; Yuan, Chengcheng; Fang, Zheng; Qin, Hong; Liu, Chengkou; Guo, Kai

doi:10.1016/j.isci.2023.108605

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Active Methylene Compounds As Substrates1

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2024

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“…In 2023, they used 2-hydroxynaphthalene-1,4-dione as the equivalent of active methylene compounds to achieve a similar reaction to furnish sulfonium diacylmethylides. [37]…”

Section: Active Methylene Compounds As Substratesmentioning

confidence: 99%

Synthesis of Sulfo(xo)nium Diacylmethylides

Fu,

2024

Eur J Org Chem

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Sulfo(xo)nium diacylmethylides (sulfur ylides) are simple, stable, readily prepared, and versatile synthons. Compared with the sulfo(xo)nium monoacylmethylides, they can be compatible with more rigorous reaction conditions and showcase unique characteristics due to their excellent stability. This concept article provides an account for the syntheses of sulfo(xo)nium diacylmethylides, including the utilization of active methylene compounds, carbene precursors, sulfo(xo)nium monoacylmethylides, and electron‐deficient alkynes as substrates, with discussions on substrate scopes, proposed mechanisms, selected product examples, and applications. Challenges for further exploration and prospect on sulfo(xo)nium diacylmethylides in the future are also suggested.

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“…In 2023, they used 2-hydroxynaphthalene-1,4-dione as the equivalent of active methylene compounds to achieve a similar reaction to furnish sulfonium diacylmethylides. [37]…”

Section: Active Methylene Compounds As Substratesmentioning

confidence: 99%

Synthesis of Sulfo(xo)nium Diacylmethylides

Fu,

2024

Eur J Org Chem

View full text Add to dashboard Cite

show abstract

Electro-oxidative quinylation of sulfides to sulfur ylides in batch and continuous flow

Cited by 1 publication

References 71 publications

Synthesis of Sulfo(xo)nium Diacylmethylides

Synthesis of Sulfo(xo)nium Diacylmethylides

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