Electroanalysis

DeFord, D. D.

doi:10.1021/ac60085a022

Cited by 5 publications

(2 citation statements)

References 38 publications

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“…Deposition of metallic ions at controlled potentials has long been used as a method to separate metals selectively. Recently the development of adequate instruments to control the cathode potential automaritally has stimulated renewed interest in this method (15,16). The reverse process, selective stripping of metals from an electrode into a solution at controlled anode potential, has not been similarly exploited for analytical separations.…”

Section: Electrolytic Strippingmentioning

confidence: 99%

Separations with a Mercury Electrode

Schmidt

Bricker²

1955

J. Electrochem. Soc.

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By means of electrolysis with a mercury cathode, microgram quantities of copper, lead, cadmium, zinc, iron, cobalt, and nickel can be separated from at least 0.51V[ vanadium solutions. Quantitative recovery of all these traces of metals except cadmium from the mercury by distillation is satisfactory, and their subsequent estimation by either polarographie or spectrophotometrie methods is adequate.Electrolytic stripping of dilute amalgams at controlled potentials shows that the electrodeposited metals could not only be separated into the two major groups of passive (Fe, Co, and Ni) and nonpassive (Cu, Pb, Cd, and Cu) metals, but that separations within the nonpsssive group are also possible.

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Section: Electrolytic Strippingmentioning

confidence: 99%

Separations with a Mercury Electrode

Schmidt

Bricker²

1955

J. Electrochem. Soc.

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“…23, 176 (1952). THIS review attempts to survey the developments in the fields of electroanalysis and coulometric titrations since the publication of the last review in this series (29). As in the previous reviews, only a few selected papers in the field of fundamental electrochemistry are included.…”

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confidence: 99%