Electrocatalytic properties of platinum particles incorporated with polypyrrole films in d-glucose oxidation in phosphate media

Becerık, I.; Kadırgan, F.

doi:10.1016/s0022-0728(97)00343-4

Cited by 51 publications

(32 citation statements)

References 15 publications

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“…In recent years there have been many reported studies on the incorporation of metal particles within a conducting polymer matrix, such as polyaniline or polypyrrole [1][2][3][4][5][6][7]. This incorporation can be achieved readily by the reduction of the appropriate metal salt at the conducting polymer interface.…”

Section: Introductionmentioning

confidence: 99%

“…For example, Becerik et al [4,12] have shown that more efficient oxidation of d-glucose occurs at palladium-or platinum-dispersed polypyrrole electrodes than at pure palladium or platinum substrates. Likewise, Guascito et al [3] have observed the oxidation of glucose in an alkaline NaOH solution at a copper-dispersed poly-3-methylthiophene substrate.…”

Section: Introductionmentioning

confidence: 99%

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Oxidation and photo-induced oxidation of glucose at a polyaniline film modified by copper particles

Farrell

Breslin

2004

Electrochimica Acta

116

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The oxidation and photo-induced oxidation of glucose at a copper-dispersed polyaniline film was studied in an alkaline hydroxide solution. It was found that the copper-dispersed polyaniline electrode was capable of oxidizing glucose at potentials between 0.2 and 0.75 V/(Ag|AgCl), with the rate of oxidation being higher than that observed at a bulk copper electrode. On irradiation of the composite with polychromatic UV light, a further increase in the rate of the glucose oxidation reaction was observed. Formate was identified as the main product of the glucose oxidation reaction under both light and dark conditions using 1 H NMR spectrometry. This suggests that illumination does not alter significantly the reaction pathway.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Oxidation and photo-induced oxidation of glucose at a polyaniline film modified by copper particles

Farrell

Breslin

2004

Electrochimica Acta

116

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“…Oxidation of D-glucose on a PPy Pt electrode recorded under the same conditions displays a similar shape. In comparison with the oxidation of D-glucose on a polycrystalline Pt electrode, the PPy Pt electrode leads to higher activity for peaks A and C. A further effect on the oxidation current density of glucose after the incorporation of platinum in the PPy matrix proves the important role of the electrode structure for the electrocatalytic process [12].…”

Section: Oxidation Of D -Glucose On the Pt (Substrate) Ppy Pt Electrodementioning

confidence: 96%

“…In our previous study we had investigated the effect of platinum deposition potential on the electrooxidation of D-glucose [12]. Values ranging from − 0.36 to − 0.66 V (MSE) were tested for platinum deposition.…”

Section: Oxidation Of D -Glucose On the Pt (Substrate) Ppy Pt Electrodementioning

confidence: 99%

“…This electrically conducting polymer allows the use of small amounts of platinum catalyst. In our previous work [12], we investigated the effect of platinum particles incorporated in polypyrrole films for D-glucose oxidation in phosphate media and determined the optimum conditions for minimum platinum loading and/or maximum current density. In order to obtain higher current densities at low oxidation potentials and so to be effective as the working anode in a glucose sensor or fuel cell, one needs to move onto bimetallic systems.…”

Section: Introductionmentioning

confidence: 99%

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Platinum–palladium loaded polypyrrole film electrodes for the electrooxidation of d-glucose in neutral media

Becerık

Süzer

Kadırgan

1999

Journal of Electroanalytical Chemistry

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Modified polymer films with metal particles incorporated into the films by electrodeposition are known as possible electrocatalysts for various electrode reactions such as fuel cell applications. This work presents some results concerning the electrooxidation of D-glucose at modified polymer film electrodes prepared on a platinum substrate. This reaction has a great deal of interest in view of its applications to detection systems (glucose sensor), fuel cells (pacemakers) and electroorganic systhesis. The modified polymer film electrodes contain platinum and/or palladium particles dispersed in the polypyrrole film by electrodeposition in neutral media. Addition of palladium to platinum modifies the electrocatalytic behaviour of the electrode drastically. The modification is thought to involve minimisation of the poisoning of the catalyst, hence increasing its electrode activity.

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Metallic‐Based Nanocomposites of Conductive Polymers

Tsakova

2010

Nanostructured Conductive Polymers

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IntroductionSince the remarkable discovery of high electrical conductivity in polymer materials in 1977 [1], studies on conductive polymers (CP 1 ) have developed into interdisciplinary research expanding in various directions. A significant impetus to the field was given by materials scientists in their attempts to combine the unique properties of conductive polymers with those of other inorganic and organic materials. Thus, in the last two decades, research on the synthesis of CP-based composite materials has flourished and resulted in the development of a great variety of new materials with interesting specifically designed properties. The accumulation of a great number of studies on nanocomposite materials has provoked the recent appearance of several review articles [2-7] attempting to summarize, from different specific points of view, the advances made in the field. Thus, electrochemical aspects [2,7] of CP-based composites, optical and electronic properties [3], polyaniline(PANI)-based nanocomposites [4], the involvement of composites of CPs in chemical sensing [5], and the incorporation of metallocenes in CPs [6] have been extensively discussed.

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Electrocatalytic properties of platinum particles incorporated with polypyrrole films in d-glucose oxidation in phosphate media

Cited by 51 publications

References 15 publications

Oxidation and photo-induced oxidation of glucose at a polyaniline film modified by copper particles

Oxidation and photo-induced oxidation of glucose at a polyaniline film modified by copper particles

Platinum–palladium loaded polypyrrole film electrodes for the electrooxidation of d-glucose in neutral media

Metallic‐Based Nanocomposites of Conductive Polymers

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